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Q.

The wave function of a molecular orbital formed by reinforce of wave functions of ΨA and ΨB of atomic orbital A and B is represented as

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a

ΨA±ΨB

b

ΨA-ΨB

c

2ΨA+ΨB

d

ΨA+ΨB

answer is A.

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Detailed Solution

An atomic orbital is an electron wave, the waves of the two atomic orbitals may be in phase
or out of phase. Suppose ΨA and ΨB represent the amplitude of the electron wave of the
atomic orbitals of the two atoms A and B.
Case 1: When the two waves are in phase so that they add up and amplitude of the wave is Φ=ΨA+ΨB

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