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Q.

The wavelength of the first member of the Balmer series in hydrogen spectrum is x A0. Then the wave length (in A0) of the first member of Lyman series in the same spectrum is

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a

527x

b

43x

c

275x

d

536x

answer is A.

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Detailed Solution

H- atom Z =1

Balmer series n1=2

First member of Balmer series n1=2 ; n2=3

v-=1λ=RHZ2(122-132)  v- =1λ=RHZ2(14-19) λ =365RH =x A0 RH =365x----------(1)

H- atom Z =1

Lymann series n1=1

First member of Lymann series n1=1 ; n2=2

v-=1λ=RHZ2(112-122)  v- =1λ=RHZ2(11-14) λ =43RH

Substituting the value of RH from (1) equation

λ =43(365x) λ =5x27

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