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Q.

The weight of KMnO4 that can oxidise 100 ml of. 0.2M oxalic acid in acidic medium is [Mol. wt of KMnO4 = 158]

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a

1.58g

b

1.264g

c

12.64g

d

15.8g

answer is B.

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Detailed Solution

2KMnO4 + 5 H2C2O4 + 6HCl  2MnCl2 + 10CO2 + 8 H2O

noxalic acid= 0.2×1001000=0.02 

From (1)

52mol of H2C2O4 require 1 mol KMnO4 = 158 g KMnO4

0.02 mol of H2C2O4 require 1 mol of KMnO4 = 1585×0.02                                                                                    = 1.26 g of KMnO4

Hence, correct option is: (B) 1.264g

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