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Q.

The weight of KMnO4 that can oxidise 100ml of. 0.2M oxalic acid in acidic medium is [Mol. wt of KMnO4 = 158]

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a

1.264 g

b

15.8 g.

c

12.64 g

d

1.58 g.

answer is B.

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Detailed Solution

                KMnO4                                                                                              

n-factor in acidic medium = 5  

MnO4-Mn+2  

Oxalic acid

n-factor = 2

C2O4-22CO2

GEW=1585g

V= 100ml

 N = 0.2(2) = 0.4N

At neutralization point ,

 V1N1= V2N2

WGEW=VN1000

     W1585=100(0.4)1000                                        

 W=1.264g

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The weight of KMnO4 that can oxidise 100ml of. 0.2M oxalic acid in acidic medium is [Mol. wt of KMnO4 = 158]