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Q.

The work done in Joules when  1.0  mole of   N2H4  decomposes against a pressure of 1.0 atm at 27° C is __________
 3N2H4(l)4NH3(g)+N2(g)

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a

9976.8

b

9976.8

c

-14965.2

d

4157.0

answer is A.

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Detailed Solution

3N2H4(l)4NH3(g)+2N2(g) 1molN2H4(l)   would produce 2 mol gases

(3molN2H4produces6molofgaseousproducts) P=1.0atm,  T=27°C=300K

Work done by system  

=PΔV=RTΔn=(8.314J/mol/K)  (300K)  (2mol)=4988.4J

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