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Q.

The H0 for the mutarotation of glucose in aqueous solution

αD-glucose (aq)β - D-glucose (αq)

has been measured in a microcalorimeter and found to be -1.16 KJ. mol-1. The enthalpies of solution of the two forms of glucose have been determined to be 

αD glucose (s)αD glucose (aq)

ΔH=10.72kJmol1

βD glucose (s)βD glucose (aq)

ΔH=4.68kJmol1

Calculate H0 (in kJ/mol) for the mutarotation of solid α-D-glucose to solid β-D-glucose :

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a

+4.88 kJ/mol

b

- 4.88 kJ/mol

c

+2.44 kJ/mol

d

-2.44 kJ/mol

answer is A.

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Detailed Solution

αD(s)βD(s)ΔH=10.724.681.16 =+4.88kJmol1

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The ∆H0 for the mutarotation of glucose in aqueous solutionα−D-glucose (aq)⟶β - D-glucose (αq)has been measured in a microcalorimeter and found to be -1.16 KJ. mol-1. The enthalpies of solution of the two forms of glucose have been determined to be α−D− glucose (s)⟶α−D− glucose (aq)ΔH∘=10.72kJmol−1β−D− glucose (s)⟶β−D− glucose (aq)ΔH∘=4.68kJmol−1Calculate ∆H0 (in kJ/mol) for the mutarotation of solid α-D-glucose to solid β-D-glucose :