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Q.

The KSP of Ag2CrO4,AgCl, AgBr and Agl are respectively, 1.1×1012,1.8×1010,5.0×1013,8.3×1017.Which one of the following salts will precipitate last if AgNO solution is added to the solution containing equal moles of NaCl, NaBr, Nal and Na2CrO4

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a

AgCl 

b

AgBr 

c

Ag2CrO4

d

Agl

answer is C.

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Detailed Solution

Ag2CrO4 Ksp=Ag+2Cr2O42=1.1×1012 Ag+=1.1×1012Cr2O42 AgCl Ksp=Ag+Cl=1.8×1010 Ag+=1.8×1010Cl AgBr  Ksp=Ag+Br=5.0×1013 Ag+=5.3×1013Br Agl  Ksp=Ag+I=8.3×1017 Ag+=8.3×1017I  Ifwetake Cr2O42=Cl=Br=I=1  than maximum Ag+will be required in case of Ag2CrO4. 

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