Q.

Thermal decomposition for N2O5(g)  1st order kinetics as per N2O5(g)2NO2(g)+12O2(g) Initial presure of N2O5 is 100mm. After 10 minutes, the pressure developed is 130mm, what is rate constant?

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a

0.693 min–1

b

2.303×10-2 min-1

c

0.03 min–1

d

0.025 min–1

answer is C.

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Detailed Solution

N2O5t =100 mm2NO2+12O2 t=10 min   100-x        2x          x2

at t= 10 mins 

100-x+2x+x2=130

x = 20

K1=2.30310log100100-20=0.2303(1-0.9010)=0.02303 min-1 

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