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Q.

Thermal decomposition for N2O5( g) follows 1st  order kinetics as per N2O5( g)2NO2( g)+12O2( g). Initial pressure of N2O5 is 100 mm. After 10 minutes, the pressure developed is 80 mm, what is rate constant?

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a

2.303×10-4 min-1

b

0.693 min-1

c

0.025 min-1

d

0.03 min-1

answer is B.

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Detailed Solution

lnPoPt=Kt ln10080=K×10 0.223=K×10 K=2.23×10-2

Therefore, the correct option is (B).

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