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Q.

Thermal decomposition of gaseous X2 to gaseous X at 298 K takes place according to the following equation:X2g 2Xg

The standard reaction Gibbs energy,ΔrG0, of this reaction is positive. At the start of the reaction, there is one mole of X2 and no X. As the reaction proceeds, the number of moles of  X formed is given by β . Thus, βequilibrium  is the number of moles of  X formed  at equilibrium . The reaction is carried out at a constant total pressure of 2 bar. Consider the gases to behave ideally. (Given : R=0.083 L bar K1mol1

 

 

The INCORRECT statement among the following , for this reaction, is 

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a

Decrease in the total pressure will result in formation of more moles of gaseous X

b

At the start of the reaction, dissociation of gaseous X2 takes place spontaneously 

c

βequilibrium=0.7

d

Kc<1

answer is C.

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