Q.

Thermal decomposition of HI(g) on Gold surface follows Zero order kinetics. With initial pressure 1000 mm. If the pressure after 20sec is 960 mmw.r.t HI(g), rate constant is (in mmsec-1 )

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a

2

b

28

c

40

d

20

answer is C.

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Detailed Solution

Thermal decomposition of HI on gold surface, is an example of zero order reaction as the concentration of the gaseous reactant on the metal surface remains constant. This is because, as the reactants react off on the surface, more molecules are adsorbed on the surface and rate remains constant throughout.

Therefore, the correct option is (C).

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