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Q.

Three closed vessels A, B and C are at the same temperature T and contain gases which obey the Maxwellian distribution of velocities. Vessel A contains only O2, B only N2 and C a mixture of equal quantities of O2 and N2. If the average speed of the O2 molecules in vessel A is v1, that of the N2  molecules in vessel B is v2, then, average speed of the O2 molecules in vessel C is :

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a

V1V21/2

b

V1

c

3kT/M

d

V1+V22

answer is B.

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Detailed Solution

Three closed vessels A, B and C are at the same temperature T and contain gases which obey the Maxwellian distribution of velocities. Vessel A contains only O2, B only N2 and C a mixture of equal quantities of O2 and N2. If the average speed of the O2 molecules in vessel A is v1, that of the N2  molecules in vessel B is v2, then, average speed of the O2 molecules in vessel C is v1.

Both O2 and N2 gases in vessel C will behave independently since, Vav=8RTπMdepends only on the temperature and mass of the gas molecule, there is no difference between the Vavof O2 in vessel A and C is v1.

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