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Q.

Three complexes  (I) [CoCl(NH3)5]+2 (II)  [Co(NH3)5 H2O]+2 (III) [Co(NH3)6 ]+3 absorb light in the visible region .The correct order of wavelength of light absorbed by them is

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a

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b

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c

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d

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answer is C.

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Detailed Solution

  • A complex having a strong field ligand has the tendency to absorb light of the highest energy. Among the three complexes, 

[Co(NH3)6 ]+3 will absorb radiation of the highest energy and least wavelength.

[Co(NH3)5H2O]+2  has a weaker field than the above compound and therefore absorbs radiation of lesser energy and more wavelength.

 [CoCl(NH3)5]+2has the weakest field and therefore will absorb light of least energy and highest wavelength. 

Strength of ligand: NH3​>H2O>Cl-

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