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Q.

Three elements chromium, manganese and iron have heat of atomizations 400 kJ, 420 kJ and 280 kJ per 1 mole of metal but not respectively. Arrange the values in the order for chromium, manganese and iron in kJ/mol.

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a

400, 420, 280

b

420, 400, 280

c

400, 280, 420

d

280, 400, 420

answer is C.

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Detailed Solution

Both chromium and manganese have stable d5 configuration and the d-orbitals are reluctant to participate the d5 configuration is more stable since in chromium d5 configuration is anomalous. So manganese has low heat of atomization than chromium. In iron having d6 configuration the 4 unpaired electrons can participate in bonding effecting. So iron has more heat of atomization than chromium and manganese

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