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Q.

Three grams each of magnesium and oxygen were allowed to react. Assuming that the reaction is complete to form MgO, the substance left unreacted is

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a

1.5 g of Mg

b

1.0 g of Mg

c

1.0 g of O2

d

1.5 g of O2

answer is A.

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Detailed Solution

No. of moles of magnesium = weight /MW=3/24=0.125moles

No. of moles of oxygen = weight /MW=3/32=0.094moles

The balanced equation for the formation of MgO is

2Mg+O22MgO

2 moles of magnesium react with 1 mole of oxygen to form 2 moles of MgO

0.125 moles of magnesium react with 0.125/2=0.0625 moles of oxygen

From the above calculations it is concluded that oxygen is present in excess amount than magnesium. Magnesium is the limiting reagent

Moles of excess oxygen left = actual moles - reacted moles =0.094-0.0625=0.0315moles.

From the formula Moles = weight/MW, we can calculate the oxygen left unreacted 0.0315=W/32

W=0.0315×32=1.008 g

Hence the correct option is (D).

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