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Q.

Three moles of AgCl get precipitated when one mole of an octahedral coordination compound with the empirical formula CrCl3·3NH3.3H2O reacts with an excess silver nitrate. The number of chloride ions satisfying the secondary valency of the metal ion is ____

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Detailed Solution

The amount of Cl- present in the ionization sphere is equal to the amount of precipitated AgCl.

CrH2O3NH33Cl3CrH2O3NH333++3Cl-AgNO3AgCl

           1 mole                                       1 mole                     3 mole             3 mole

Due to the absence of Cl- in the coordination sphere. The answer is zero as a result.

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