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Q.

Tick the correct statement on the aufbau principle?

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a

5f is lower in energy than 7s

b

(n - 1 )d subs hell always has energy more than ns subshell

c

(n - 1)d subshell is always lower in energy than ns subshell

d

5d is lower in energy than 4f

answer is B.

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Detailed Solution

Energy of ‘(n–1)d’ subshell is slightly greater than ‘ns’ subshell, hence "ns" orbital is filled first then (n – 1) d orbitals.

As per n+l rule (n+1)d  subshell should have higher energy than "ns" subshell.

Energy increases with increase in the value of n+l
nf subshell should have higher energy than (n+2)s subshell.

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Tick the correct statement on the aufbau principle?