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Q.

Titration of 100 ml of 0.1 M Na2CO3(ka1 of H2CO3=10-7 and ka2 of H2CO3=10-11)  solution with 0.1 M HCl solution. Which of the following is suitable indicator?

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a

Phenolphthalein for 1st equivalence point

b

Methyl orange for 2nd equivalence point

c

Phenolphthalein for 2nd equivalence point

d

Methyl orange for 1st equivalence point

answer is A, B.

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Detailed Solution

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Na2CO3+HClNaHCO3+NaClpHofsolinrangeofphenolpthaline NaHCO3+HClNaCl+H2CO3

pH of soln in range of Methyl orange 

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