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Q.

To a 100 g an oleum sample labelled as ‘118% oleum’, 9g of water is added. Select the correct option(s).

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a

% w/w of SO3 is nearly 36.7%

 

b

It contains only H2SO4, SO3and SO2

c

It contains H2SO4, SO3and H2O.

d

New solution will have labelling 109%

answer is D.

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Detailed Solution

118% oleum means in 100g oleum by adding 18g water it gives 118g  H2SO4   nH2O added =  nSO3  Present in 100g oleum by adding 9g or 12 mole water 12 mole SO3 change into H2SO4 and  mole SO3 = 40g SO3 present in 109g oleum
%wt  ofSO3=40109×100=36.7%
 

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