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Q.

To a 200 mL of 0.1 M acid HA solution 90 mL of 0.1 M solution of NaOH be added. Now, what volume of 0.1 M NaOH be added into above solution so that pH of resulting solution be 5?

Kα(HA)=105

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a

10 mL

b

15 mL 

c

2 mL

d

20 mL

answer is C.

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Detailed Solution

HA+       OH       A+      H2O

 20                 9                   -

 11                 -                   9

 11             0.1×V         9

110.1×V -             9+0.1×V

pH=pKa=5

A=[HA] or V=10ml

Hence, option C is correct.

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