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Q.

To an acidified dichromate solution, a pinch of Na2O2 is added and shaken. What is observed?

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a

bluish-green ppt

b

blue colour appears and disappear

c

evolution of oxygen

d

Orange colour changes to green

answer is B, C, D.

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Detailed Solution

Cr2O72+10H++4Na2O2CrO5blue   colour+8Na++5H2O 
In absence of  ether, CrO5   decomposes  to Cr3+  with the evolution of  O2
4CrO5+12H+4Cr3+green+7O2+6H2O
 

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