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Q.

To avoid the precipitation of Hydroxides of Zn2+,Mn2+ and  Ni2+ along with those of Fe3+ , Al3+  and Cr3+ the third group solution should be :

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a

Concentrated HNO3 is added

b

Treated with excess of NH4Cl

c

Concentrated H2SO4 is added

d

Treated with excess of  NH4OH

answer is B.

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The third group solution should be treated with excess of NH4Cl

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