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Q.

To convert 12g of NaH2PO4 completely into Na3PO4, the volume of 1 molar NaOH required is cm3 (nearest integer)

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answer is 200.

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Detailed Solution

NaH2PO4( s)+2NaOH(aq)Na3PO4(aq)+2H2O(l)
Moles of NaH2PO4=12120=0.1 moles
0.1 moles of NaH2PO4 required 0.2 moles of NaOH.

Given that there is 1 mole of NaOH in 1000 ml of solution.
Consequently, 0.2 moles of NaOH 0.2×1000.
So, 200 ml is the required volume.

Hence, the correct answer is 200 ml.

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