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Q.

To find the standard potential of M3+/M electrodes the following cell is constituted. Pt M/M3+(0.001mol  L1)/Ag+(0.01molL1)/Ag the emf of the cell is found to be 0.421 volt at 298K. the standard potential of half reaction M3++3eM  at 298K will be GivenEAg+/Ag0at298K=0.80Volt ) 
 

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a

0.38 Volt

b

0.32 Volt

c

1.28 Volt

d

0.66 Volt

answer is B.

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Detailed Solution

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EM3+/MEM3+/MCell reaction
M+ 3 Ag+ (aq)    = 0.32 volt 
E = Eo  -   Question Image log  Question Image
0.421= E0  -  1.732 log  0.001(0.01)3 
E0 =0.48
 E=EAg+/AgEM3+/M
 = 0.8v – 0.48v = 0.32 volt
 

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