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Q.

To the product obtained by the reaction of ozone with sodium nitrite, freshly prepared ferrous sulphate & conc. H2SO4 are added. Regarding the product formed in this reaction, which of the following statements are correct

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a

Oxidation number of nitrogen in the brown species is +3

b

Magnetic moment of Fe+2 becomes zero due to pairing of electrons

c

Brown colour appears due to charge transfer

d

The Brown coloured species is paramagnetic

answer is A, B, C.

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Detailed Solution

a, b are conceptual
c) In brown ring NO+ is formed due to transfer of electron of electron from the anti bonding orbital present near to nitrogen. So, Oxidation number of nitrogen increases.

(d) Fe+2 = [Ar]3d64s0 ; no. of unpaired electrons=4

so magnetic moment may not be zero.

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