Q.

To 500 cm3 of water, 3.0 x 10-3 kg of acetic acid is added. If 23% of acetic acid is dissociated, what Will be the depression in freezing point? Kr and density of water are 1.86K kg mole-1  and 0.997 g cm-3 respectively

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a

0.228 K 

b

 0.556 K 

c

0.186 K 

d

0.372 K 

answer is B.

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Detailed Solution

Depression in Freezing point is a colligative  property observed  in solutions that results from the introduction of solute molecules to a solvent.

Another formula is ,

ΔTf=ikfm                     i=Van't Hoff factor

ΔTf=(1+0.23)×1.86×3×103×10360500×0.997×1000=0.229K

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