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Q.

Toluene FeCl3X2P  incorrect statement is 

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a

P is a mixture of ortho para chlorotoluene 

b

Fluorination is highly reactive and explosive 

c

P is benzyl halide

d

Iodination requires HIO4&HNO3orHIO3

answer is A.

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Detailed Solution

X2/Lewis acid - electrophilic substitution reaction on benzene

X2|hV(or) X2|Δfree radical substitution on benzylic carbon 

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-CH3 group due to +I, +R (H.C) is an o, p-directing group

Iodination

Along with the major & minor products HI is the byproduct 

HI reduces these iodoarenes back to toluene 

It is reversible 

It is better carried out in presence of oxidants like HIO3,HIO4 (or) HNO3

They oxidize HI to I2 and prevent backward reaction. Fluorination is explosive 

P is benzyl halide is false. 

‘P’ would be the product when sunlight is used. 

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