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Q.

Total vapour pressure of mixture of 1 mole of volatile component  APA0=100  mm  Hgand 3 mole of volatile component BPB0=80  mm  Hgis 90  mm  Hg. For such case:

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a

all  the above statements are correct

b

there is positive deviation from Raoult’s law

c

force of attraction between A and B is smaller than that between A and A or between B and B

d

boiling point has been lowered

answer is D.

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Detailed Solution

Pideal=PA0xA+PB0xB

100×14+80×3485  mm  Hg

Pactual=90  mm  Hg

  Actual v.pr. is greater than ideal solution v.pr. so +ve deviation from Raoult’s law.

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