Q.

Toulene when heated with Alkaline KMnO4 followed by acidification gives ‘A’. A on decarboxylation gives B. B in presence of CO + HCl / CuCl gives C. The reaction B   C is

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a

Gattermann-Koch reaction

b

Stephen’s reaction

c

MPV reduction

d

Etard reaction

answer is A.

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Detailed Solution

When benzene is treated with carbon monoxide in an acidic medium in presence of anhydrous aluminium chloride, it results in the production of benzaldehyde. This reaction is a name reaction, popularly known as Gattermann-Koch reaction..

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