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Q.

Towards, nucleophilic substitution chlorobenzene is

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a

As reactive as methyl chloride

b

More reactive than ethyl chloride

c

More reactive than isopropyl chloride

d

Less reactive than benzyl chloride

answer is D.

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Detailed Solution

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In chlorobenzene, the halogen atom is bonded to the highly electronegative sp2 hybridised carbon atom. So, nucleophilic substitution reaction is not possible.
Hence, two reasons for less reactivity of chlorobenzene towards nucleophilic substitution reactions are resonance in chlorobenzene and sp2 hybridised nature of carbon atom bonded to chlorine atom.

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