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Q.

Transition metals and their compounds catalyse reactions because

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a

they have  competely filled s-subshell

b

they introduce an entirely new reaction mechanism with a lower activation energy

c

they have variable oxidation states differ by two units

d

they have a comparable size due to poor shielding of d-subshell

answer is C.

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Detailed Solution

The following explanation explains why transition metals have catalytic activity. Transition metals occasionally produce unstable intermediate molecules due to their fluctuating oxidation states, opening up a novel reaction pathway with a lower activation energy. They present a completely new, lower-activation energy response mechanism.

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