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Q.

Trichloroacetaldehyde was subjected to Cannizzaro’s reaction by using NaOH. The mixture of the products contains sodium trichloracetate ion and another compound. The other compound is

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a

Trichloromethanol

b

Chloroform

c

2,2,2-Trichloropropanol

d

2,2,2-Trichloroethanol

answer is A.

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Detailed Solution

  • CCl3CHO→NaOHCCl3COONa+CCl3CH2OH
  • Cannizzaro reaction is a disproportionation reaction.
  • Aldehyde molecules are oxidized to the carboxylic acid salt and the other one is reduced to alcohol.
  • IUPAC name for the compound is 2,2,2- Trichloroethanol.
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