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Q.

Tungsten is obtained commercially by the reduction of WO3 with H2 according to the equation

WO3(s)+3H2(g)W(s)+3H2O(g)

The following data related to this reaction at 25° C are available.

                          WO3(s) H2O(g)

ΔHkJ/mol840.3241.8ΔGkJ/mol763.5228.5

The temperature at which this reaction is at equilibrium at 1 atm is closest to which of the following?

 

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a

213 K

b

2810 K

c

928 K

d

124 K

answer is C.

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Detailed Solution

ΔGRxn=3×228.5+763.5=78ΔHRxn=3×241.5+840.3=115.8ΔS=115.878298=37.8298T=115.837.8×298=913K

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