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Q.

Twenty milliliters of an aqueous solution of 0.10M butyric acid is shaken with 10ml ether. After the layers are separated , it is determined by the titration that 0.5 mmol butyric acid remains in the aqueous layer. The percent of acid extracted is

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answer is 75.

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Detailed Solution

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volume of aq sol=20(v)
Volume of ether=10(v)
Unextracted amount $w_{n}$ =0.5mm
0.1m= $\frac{n}{v} = \frac{n}{20}$ X1000 $\Rightarrow$ n=2mmoles
Extracted amount =2.05
=1.5
% of entr $\frac{1.5}{2}$ X100=75%

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