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Two aqueous solutions of ${KNO}_{3}$ and ${CH}_{3} COOH$ are prepared separately. Molarity of both the solutions is 0.1 M and osmotic pressures are $P_{1}$ and $P_{2}$ respectively. The correct relationship between their osmotic pressures is :

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$P_{1} = P_{2}$

$\frac{P_{1}}{P_{1} + P_{2}} = \frac{P_{2}}{P_{1} + P_{2}}$

$P_{1} > P_{2}$

$P_{2} > P_{1}$

answer is C.

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Detailed Solution

KNO₃ ( uni-uni valent) is a strong electrolyte which is more ionised than CH₃COOH (uni-uni valent) is a weak electrolyte.

$i_{{KNO}_{3}} > i_{{CH}_{3} COOH} ∴ P_{1} > P_{2}$

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