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Q.

Two aqueous solutions of KNO3 and CH3COOH are  prepared separately. Molarity of both the solutions is 0.1 M and osmotic pressures are P1 and P2 respectively. The correct relationship between their osmotic pressures is : 

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a

P1=P2

b

P1P1+P2=P2P1+P2

c

P1>P2

d

P2>P1

answer is C.

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Detailed Solution

KNO3 ( uni-uni valent) is a strong electrolyte which is more ionised than CH3COOH (uni-uni valent) is a weak electrolyte.

 iKNO3>iCH3COOH  ∴ P1>P2

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