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Q.

Two chamber containing m1and m2 grams of a gas at pressures P1and P2 respectively are put in communication with each other, temperature remaining constant. The common pressure reached will be 

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a

P1P2m1+m2P2m1+P1m2

b

P1P2m1P2m1+P1m2

c

m1m2(P1+P2)P2m1+P1m2

d

m1m2P2P2m1+P1m2

answer is A.

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Detailed Solution

According to Boyle's law, PV = kT (a constant)

or   pmρ=kT or ρ=PmkT

or ρ=PK                  (where kTm=K a constant)

So, ρ1=P1K and V1=m1ρ1=m1P1/K=Km1P1

Similarly, V2=Km2P2

Total Volume = V1+V2=Km1P1+m2P2

Let P be the common pressure and ρbe the common density
of mixture. Then,

ρ=m1+m2V1+V2=m1+m2Km1P1+m2P2

Therefore , P=Kρ=m1+m2m1P1+m2P2=P1P2m1+m2m1P2+m2P1

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