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Two compounds [Cr(NH₃)₅Br]Cl and [Cr(NH₃)₅Cl]Br can be distinguished by reagent A and the two compounds exhibit isomerism (B). Then (A) and (B) are

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BaCl₂, ionisation

AgNO₃, Co-ordination

AgNO₃, ionisation

BaCl₂, Co-ordination

answer is A.

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Detailed Solution

[Cr(NH₃)₅Br]Cl and [Cr(NH₃)₅Cl]Br shows ionisation isomerism and can be distinguished using AgNO₃.

AgNO₃ reacts with Cl⁻ of [Cr(NH₃)₅Br]Cl to form white precipitate of AgCl. When Br⁻ of [Cr(NH₃)₅Cl]Br reacts with silver ion of AgNO₃, a pale yellow precipitate of AgBr is formed.

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