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Q.

Two compounds [Cr(NH3)5Br]Cl and [Cr(NH3)5Cl]Br can be distinguished by reagent A and the two compounds exhibit isomerism (B). Then (A) and (B) are

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a

BaCl2, ionisation

b

AgNO3, Co-ordination

c

AgNO3, ionisation

d

BaCl2, Co-ordination

answer is A.

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Detailed Solution

[Cr(NH3​)5​Br]Cl and [Cr(NH3​)5​Cl]Br shows ionisation isomerism and can be distinguished using AgNO3​.

AgNO3 reacts with Cl of [Cr(NH3)5Br]Cl to form white precipitate of AgCl. When Br of [Cr(NH3)5Cl]Br reacts with silver ion of AgNO3, a pale yellow precipitate of AgBr is formed.

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