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Q.

Two containers are connected by a tube of negligible volume, container (I) has  N2 (g) gas at a pressure 4 atm and temperature  T (K) and container (II) has 1 liter H2O (1) at temp (T) initially.  Find correct option(s) after stopcock is removed.  (aq.tension=190 torr) (assume container II has water vapour only)
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a

Pressure of N2=2.0 atm     

b

Total pressure=1.95 atm

c

Total pressure =2.25 atm

d

Pressure of  H2O(g)  is 0.25 atm

answer is A, B, D.

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Detailed Solution

PH2o  remains same  =190760=0.25atm
PN2  finally =2.0 atm
(Since, volume is doubled)
Total pressure=2.25 atm
 

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