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Q.

Two containers of equal volume contain the same gas at pressure at P1 and P2 and absolute temperature T1 and T2 respectively. On joining the vessels, the gas attains a common pressure  P and common temperature T. The ratio is equal to   


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a

P1T1+P2T2

b

12P1T1+P2T2

c

P1T2T1+P2T1T2

d

P1 + P2T1 + T2 

answer is B.

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Detailed Solution

We know that
Ideal gas Eqn.
PV = NKT
Let the volume of gas in each container be V.
From Ideal Gas Eqn.
P1V=N1KT1
N1 = P1VKT1
For second container
P2V=N2KT2
N2 = P2VKT2
Total volume of gas
V + V = 2V
The total number of molecules in the gas
 N1+N2 = N
P(2V)KT = P1VKT1 + P2VKT2
2PT = P1T1+P2T2
PT = 12P1T1+P2T2
 
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