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Q.

Two elements A and B form compounds having molecular formulae AB2 and AB4.When dissolved in 20.0 g of Benzene, 1.00 g of AB2 lowers f.p. by 2.3C whereas 1.00g of AB4 lowers f.p. by 1.3C. The molal depression constant for benzene is 5.1. The atomic masses of A and B are respectively :

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a

can't be predicted

b

42.6, 25.59

c

30.60

d

25.59, 42.6

answer is D.

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Detailed Solution

2.3×M1+2M2=1.3×M1+4M2 0.77M1=0.46M2 1.67M1=M2

Now, use, ΔTb=Kb×M.

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