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Q.

Two elements A and B have atomic masses 40 and 60 respectively. If 40 form hcp arrangements and A is occupying 13 of the tetrahedral voids, then what will be number of  hexagonal primitive unit cells w.r.t.  B atoms in 130 mg of the substance? (Given :NA=6×1023

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a

1.0×1020

b

4.5×1020

c

4×1020

d

1.2×1021

answer is B.

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Detailed Solution

1 mole A2B3=6×1023260g of A2B3=6×10231g=6×1023260130mg=6×1023260×1301000=3×1020

with respect to B=3×1020×32 =4.5×1020

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