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Q.

Two flasks of equal volume are connected by a narrow tube (of negligible volume) all at 27° C and contain 0.70 moles of 'H2 at 0.5 atm. One of the flask is then immersed into a bath kept at 127° C, while the other remains at 27° C. The number of moles of H2 in flask 1 and flask 2 (at 127° C) are:

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a

Moles in flask 1 = 0.4, Moles in flask 2 = 0.3

b

Moles in flask 1 = 0.2, Moles in flask 2 = 0.5

c

Moles in flask 1 == 0.3, Moles in flask 2 = 0.4

d

Moles in flask 1 = 0.4. Moles in flask 2 = 0.2

answer is A.

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Detailed Solution

It is known that;

n1=0.5714×17.2410.0821×4000.3

 n2=0.4

The value of volume after putting the value in the above formula is Moles in flask 1 = 0.4, Moles in flask 2 = 0.3

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