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Q.

Two flasks X and Y have capacity 1L and 2L respectively and each of them contains 1mole of a gas. The temperature of the flasks are so adjusted that average speed of molecules in X is twice as those in Y. The pressure in flask X would be

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a

8 times of that in Y

b

same as that in Y

c

twice of that in Y

d

half of that in Y

answer is D.

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Detailed Solution

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According to Kinetic theory of gases,

PV=13mnu2

where, P is pressure of the gas, m is mass of the gas, n is no. of molecules and u is the average speed of the molecules of the gas.

So, for gas present in flask X and Y will have the pressure as follows

PX=1mnXuX23VX-----i

PX=1mnYuY23VY-----ii

According to question,
uX=2uY and nX=nY1 mole of the gas is present in each flask

2VX=VY

Dividing eqn. (i) by (ii),

PXPY=1/3nXuX2VY1/3nYuY2VX =4×2=8

PX=8PY

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