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Q.

Two gaseous equilibriums SO2(g)+12O2(g)SO3(g)& 2SO3(g)+ 2SO2(g)+O2(g)have equilibrium constants K1 & K2 respectively at 298 K. Which of the following relationship between  K1 & K2 is correct 

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a

K2=1K1

b

K2=1K12

c

K2=K12

d

K1=K2

answer is C.

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Detailed Solution

The given reactions are as follows below. 

SO2+12O2SO2 ; 2SO22SO2+O2

K1=SO3SO2O21/2  K2=SO2O2SO32

1K1=SO2O21/2SO3 and then 1K12=SO22O2SO32=K2 K2=1K12

Therefore, the correct answer is option “C”.

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Two gaseous equilibriums SO2(g)+12O2(g)→SO3(g)& 2SO3(g)+ 2SO2(g)+O2(g)have equilibrium constants K1 & K2 respectively at 298 K. Which of the following relationship between  K1 & K2 is correct