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Q.

Two gases 'A' and ' B ' are in a container. The experimental rate law for the reaction between them has been found to be rate =k[A]2[B]. Predict the effect on the rate of the reaction when the partial pressure of each reactant is doubled :
 

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a

The rate becomes eight times

b

The rate is doubled
 

c

Rate becomes four times
 

d

The rate becomes six times
 

answer is D.

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Detailed Solution

If, Rate =kx[A]2[B]1
order =3.
If pressure is increased by factor of 2 , then rate will be increased by factor of 23=8

 Rate becomes eight times..  

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