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Q.

Two I-order reactions have half-lives in the ratio 8 : 2. Calculate the ratio of time intervals t1 , t2 . Where t1 is the time period for 25 % completion of the first reaction and t2 , for 75 % completion of the second reaction.

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a

0.199 : 1

b

0.311 : 1

c

0.420 : 1

d

0.273 : 1

answer is A.

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Detailed Solution

The time intervals,

t1=3ln 2×ln 10075t2=2ln 2×ln 10025

The ratio of time intervals,

t1t2=320.60.480.6 t1t2=0.311

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