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Q.

Two identical containers A and B with frictionless positions contain the same ideal gas at the same temperature and the same volume V.  The mass of the gas in A is mA and that of B is mB. The gas in each cylinder is now allowed to expand isothermally to the same final volume 3V. The change in the pressure in A and B are found to be P and 2.5  P respectively. Then

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a

3mA=2mB

b

2mA=3mB

c

5mA=2mB

d

5mA=3mB

answer is C.

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Detailed Solution

T = Constant,  1V
For Chamber A,  ΔP=PiPt=nARTVnART3V=2nART3V  ------(I)
For Chamber B,  2.5ΔP=PiPt=nBRTVnBRT3V=23nsRTV ------(II)
From equations   (I)  and (II)
nAns=12.5=25mA/MmB/M=255mA=2mB

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