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Q.

Two isomeric compounds ‘A’ & ‘B’ have the formula C3H6Cl2 with Aq. KOH solution ‘A’ gives propionaldehyde and ‘B’ gives acetone. Then A & B are

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a

CH3CCl2CH3 and CH3CH2CHCl2

b

CH3CHClCHCl2 and CH3CH2CHCl2

c

CH3CH2CHCl2 and CH3CCl2CH3

d

CH3CHClCHCl2 and CH3CCl2CH3

answer is C.

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Terminal gem dihalides gives aldelydes & internal gem dihalides gives ketones on alkaline hydrolysis

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