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Q.

Two isomeric compounds ‘A’ & ‘B’ have the formula C3H6Cl2 with Aq. KOH solution ‘A’ gives propionaldehyde and ‘B’ gives acetone. Then A & B are

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a

CH3−CHCl−CHCl2 and CH3−CH2−CHCl2

b

CH3−CCl2−CH3 and CH3−CH2−CHCl2

c

CH3−CHCl−CHCl2 and CH3−CCl2−CH3

d

CH3−CH2−CHCl2 and CH3−CCl2−CH3

answer is C.

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Detailed Solution

Terminal gem dihalides gives aldelydes & internal gem dihalides gives ketones on alkaline hydrolysis

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