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Q.

Two molecules having same molecular formula are drawn for your reference

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Choose the correct statements :

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a

Pair of molecules in Set-I are structural isomers of each other

b

At least one molecule in Set-I can exhibit optical isomerism

c

A molecule represents facial and B represents meridonial isomer of the type Ma3b3

d

Set-II molecules have one more stereo isomer which is optically inactive

answer is C.

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Detailed Solution

In the facial or fac-isomer the same ligands are on a common face of a polyhedral complex. Here, molecule A represents the facial isomers.

When 3 ligands as well as metal are in single plane, then the isomer is said to be meridional.

Here, molecule B has the meridonial isomers.

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