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Q.

Two moles of air, when heated through 10 K expands by an amount of 1.66 × 10–3 m3  under a constant pressure of 105 N/m2. If Cv = 20.81 J/mole K, then Cp is,

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a

27.46J/mole K

b

19.11 J/mole K

c

 32.11 J/mole k

d

19.11J/mole k

answer is A.

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Detailed Solution

Delta W = P times Delta V = {10^5} times 1.33 times {10^{ - 3}}J

Rightarrow Delta W = 133J

Delta U = n{C_V}Delta T = 2 times 20.81 times 10J

Rightarrow Delta U = 416.2J

Now, Delta Q = Delta U + Delta W

= (416.2+133)J

= 529.2 J

Also, Delta Q = n{C_P}Delta T

therefore {C_P} = frac{{Delta Q}}{{nDelta T}} = frac{{549.2}}{{2 times 10}}J/mol - K

= 27.46J/mol - K

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